Monel 400 (UNS N04400)

1.Basic Information

    ItemDetails
    Alloy GradeMonel 400
    UNS NumberN04400
    European NormW.Nr. 2.4360, 2.4361
    Chinese StandardNS331
    Alloy TypeNickel-Copper (Ni-Cu) Solid Solution Strengthened Corrosion-Resistant Alloy
    Key FeatureExcellent resistance to seawater, brine, and acidic/alkaline environments, with high mechanical strength and good formability

    2. Chemical Composition (ASTM B127 / ASTM B164 Standard, wt%)

    ElementMin.Max.
    Nickel (Ni) (incl. Co)63.0%70.0%
    Copper (Cu)28.0%34.0%
    Iron (Fe)2.5%
    Manganese (Mn)2.0%
    Carbon (C)0.3%
    Silicon (Si)0.5%
    Sulfur (S)0.024%

    3.Mechanical Properties (Annealed Condition, Room Temperature)

    PropertyTypical ValueASTM B164 Requirement
    Ultimate Tensile Strength (UTS)≥ 550 MPa (80 ksi)≥ 485 MPa (70 ksi)
    Yield Strength (0.2% Offset)≥ 240 MPa (35 ksi)≥ 170 MPa (25 ksi)
    Elongation (in 50mm)≥ 45%≥ 35%
    Hardness (Brinell, HB)110 ~ 150≤ 180
    Modulus of Elasticity179 GPa (26×10⁶ psi)

    4. Corrosion Resistance (Core Selling Points)

    Seawater & Brine Resistance: Outstanding resistance to seawater corrosion at all temperatures up to boiling point, with excellent resistance to pitting and crevice corrosion. Superior to 316L stainless steel in marine environments. Acid & Alkali Resistance: Resistant to sulfuric, hydrochloric, hydrofluoric, and organic acids. Excellent performance in alkaline solutions (sodium hydroxide, caustic soda). Chloride Stress Corrosion Cracking (SCC) Resistance: Immunity to chloride-induced SCC, ideal for marine and offshore applications. Hydrofluoric Acid Resistance: One of the few alloys resistant to anhydrous hydrofluoric acid and hydrogen fluoride gas. Atmospheric Corrosion: Resistant to atmospheric corrosion in industrial and marine environments, with a stable, protective oxide film.

    5. Physical Properties

    PropertyTypical Value
    Density8.80 g/cm³ (0.317 lb/in³)
    Melting Range1300~1350°C (2372~2462°F)
    Coefficient of Thermal Expansion (20~100°C)13.9×10⁻⁶ /°C (7.7×10⁻⁶ /°F)
    Thermal Conductivity (20°C)21.8 W/(m·K)
    Specific Heat Capacity (20°C)427 J/(kg·K)
    Magnetic PropertySlightly magnetic (low permeability)

    6. Fabrication & Welding

    Heat Treatment: Solution annealing at 870~900°C (1600~1650°F), followed by rapid air cooling or water quenching to ensure optimal corrosion resistance and mechanical properties. Welding: Compatible with TIG, MIG, SMAW, and SAW processes. Recommended filler wire: ERNiCu-7. No post-weld heat treatment required for corrosion resistance. Cold Working: Excellent formability for cold bending, stamping, and deep drawing, with moderate work hardening rate. Hot Working: Hot forging and hot rolling at 900~1150°C (1650~2100°F), followed by solution annealing. Machining: Similar to austenitic stainless steel, use carbide tools with moderate speed and high feed.

    7. Typical Applications

    Marine: Seawater piping, heat exchangers, propeller shafts, marine hardware Chemical processing: Hydrofluoric acid reactors, alkylation units, caustic soda equipment Oil & gas: Downhole tubing, sour gas production equipment Aerospace: Aircraft fuel and hydraulic line components Power generation: Condenser tubes, desalination equipment Mining: Acid leaching tanks, mining equipment

    8. Concise Version (For Post List Excerpt, Ready-to-Use)

    Monel 400 (UNS N04400)
    A nickel-copper solid solution alloy with 63-70% Ni and 28-34% Cu, offering exceptional resistance to seawater, hydrofluoric acid, and chloride stress corrosion cracking.
    High mechanical strength, excellent formability and weldability, ideal for marine, chemical, and oil & gas applications.Annealed condition: UTS ≥ 485MPa, elongation ≥ 35%, suitable for long-term service in harsh corrosive environments.